To configure PPPoE settings on your Xbox 360 console, follow these steps:
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On your console, go to My Xbox, and then select System Settings.
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Select Network Settings.
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Select Configure Network.
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On the Additional Settings tab, select PPPoE Settings.
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Use the on-screen keyboard to enter the PPPoE User Name and Password that you signed up for. Leave Service Name as Not set.
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Select Done.
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Select Apply and Test when you are prompted to do this.
To find your Xbox 360's MAC address:
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On the Dashboard, in the System area, select Network Settings
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Select Edit Settings
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Select Additional Settings
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Select Advanced Settings
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Choose either the Wired or Wireless MAC address.